Zespół Katalizy Środowiskowej


Skład Zespołu
Dr hab. Andrzej Adamski, prof. UJ – kierownik Zespołu
Dr Beata Kultys
Dr Katarzyna Zięba
Dr Piotr Legutko

Doktoranci
Mgr inż. Paweł Rybowicz

Badania w obszarze katalizy środowiskowej i zrównoważonego rozwoju:
  • synteza i charakterystyka katalizatorów aktywnych w procesach usuwania tlenków azotu, lotnych związków organicznych oraz sadzy;
  • badania strukturalno-funkcjonalne katalizatorów suchego reformingu metanu;
  • projektowanie tlenkowych katalizatorów nośnikowych;
  • charakterystyka i proekologiczne wykorzystanie popiołów z sektora energetycznego;
  • kontrola procesów transportu na granicy faz ciało stałe-roztwór;
  • chemiczne procesy i technologie zrównoważone w energetyce i gospodarce odpadami.
Publikacje:
    2021
  1. J. Gryboś, M. Fedyna, P. Legutko, B. Leszczyński, J. Janas, A. Wach, J. Szlachetko, X. Yu, A. Kotarba, Z. Zhao, Z. Sojka, Mechanistic Insights into Oxygen Dynamics in Soot Combustion over Cryptomelane Catalysts in Tight and Loose Contact Modes via 18O2/16O2 Isotopic Variable Composition Measurements – A Hot Ring Model of the Catalyst Operation, ACS Catalysis 11 (2021) 9530–9546 DOI: 10.1021/acscatal.1c02152
  2. M. Fedyna, P. Legutko, J. Gryboś, J. Janas, X. Yu, Z. Zhao, A. Kotarba, Z. Sojka, Screening investigations into the effect of cryptomelane doping with 3d transition metal cations on the catalytic activity in soot oxidation, NO2 formation and SO2 resistance, Applied Catalysis A: General 624 (2021) 118302 DOI: 10.1016/j.apcata.2021.118302
    3. 2020
  3. P. Legutko, J. Gryboś, M. Fedyna, J. Janas, A. Wach, J. Szlachetko, A. Adamski, X. Yu, Z. Zhao, A. Kotarba, Z. Sojka, Soot Combustion over Niobium-Doped Cryptomelane (K-OMS-2) Nanorods—Redox State of Manganese and the Lattice Strain Control the Catalysts PerformanceCatalysts 10 (2020) 1390DOI: 10.3390/catal10121390
  4. P. Rybowicz, M. Mochnaczewski, M. Kozieł, Ł. Uruski, A. Łagosz, M. Michalik, L. Chmielarz, A. Adamski, Key Parameters of Fly Ashes Generated from the Industrial Energy Sector Decisive for Their Pro-ecological Applications, Energy & Fuels 34 (2020) 6229–6238DOI: 10.1021/acs.energyfuels.9b04426
  5. G. Grzybek, M. Greluk, P. Indyka, K. Góra-Marek, P. Legutko, G. Słowik, S. Turczyniak-Surdacka, M. Rotko, Z. Sojka, A. Kotarba, Cobalt catalyst for steam reforming of ethanol–Insights into the promotional role of potassium, International Journal of Hydrogen Energy 45 (2020) 22658-22673 DOI: 10.1016/j.ijhydene.2020.06.037
  6. K. Zięba, E. Szostak, K. Czekońska, P. Miśkowiec, A. Moos-Matysik, A. Nyczyk-Malinowska, H. Szentgyörgyi, Usefulness of bee bread and capped brood for the assessment of monocyclic aromatic hydrocarbon levels in the environment, Environmental Pollution, 265, part A (2020) DOI: 10.1016/j.envpol.2020.114882
  7. A. Auxéméry, B. Botello Frias, E. Smal, K. Dziadek, G. Philippot, P. Legutko, M. Simonov, S. Thomas, A. Adamski, V. Sadykov, K. Parkhomenko, A.-C. Roger, C. Aymonier, Continuous supercritical solvothermal preparation of nanostructured ceria-zirconia as supports for dry methane reforming catalysts, The Journal of Supercritical Fluids 162 (2020) 104855 DOI: 10.1016/j.supflu.2020.104855
    8. 2019
  8. A. Adamski, P. Legutko, K. Dziadek, M. Michalik, V.A. Sadykov, Dry reforming of methane on supported catalysts based on nickel as an example of technology limiting emission level of greenhouse gases | [Suchy reforming metanu na katalizatorach nośnikowych zawierających nikiel jako przykład technologii ograniczającej poziom emisji gazów cieplarnianych]Przemysł Chemiczny 98 (2019) 1158-1161 DOI: 10.15199/62.2019.7.26
  9. A. Adamski, P. Legutko, K. Dziadek, K. Parkhomenko, C. Aymonier, V.A. Sadykov, A.-C. Roger, Role of CeO2-ZrO2 Support for Structural, Textural and Functional Properties of Ni-based Catalysts Active in Dry Reforming of Methane, E3S Web of Conferences 108, 02018 (2019) DOI: 10.1051/e3sconf/201910802018
  10. R. Shen, J. Xie, Y. Ding, S. Liu, A. Adamski, X. Chen, X. Li, Carbon Nanotube-Supported Cu3P as High-Efficiency and Low-Cost Cocatalysts for Exceptional Semiconductor-Free Photocatalytic H2 Evolution, ACS Sustainable Chemistry & Engineering 7 (2019) 3243-3250 DOI: 10.1021/acssuschemeng.8b05185
  11. P. Legutko, J. Pęza, A. Villar Rossi, M. Marzec, T. Jakubek, M. Kozieł, A. Adamski, Elucidation of Unexpectedly Weak Catalytic Effect of Doping with Cobalt of the Cryptomelane and Birnessite Systems Active in Soot Combustion, Topics in Catalysis 62 (2019) 599-610 DOI: 0.1007/s11244-019-01132-x
    12. 2018
  12. X. Lu, J. Xie, S. Liu, A. Adamski, X. Chen, X. Li, Low-Cost Ni3B/Ni(OH)2 as an Ecofriendly Hybrid Cocatalyst for Remarkably Boosting Photocatalytic H2 Production over g-C3N4 Nanosheets, ACS Sustainable Chemistry & Engineering 6 (2018) 13140-13150 DOI: 10.1021/acssuschemeng.8b02653
  13. P. Stelmachowski, P. Legutko, T. Jakubek, A. Kotarba, Phase evolution and electronic properties of cryptomelane nanorods, Journal of Alloys and Compounds 767 (2018) 592-599 DOI: 10.1016/j.jallcom.2018.07.147
    14. 2017
  14. A.N. Shmakov, S.V. Cherepanova, D.A. Zyuzin, Y.E. Fedorova, I.A. Bobrikov, A.-C. Roger, A. Adamski, V.A. Sadykov, The crystal structure of compositionally homogeneous mixed ceria-zirconia oxides by high resolution X-ray and neutron diffraction methods, Open Chemistry 15 (2017) 438-445
  15. M.Yu. Smirnova, A.S. Bobin, S.N. Pavlova, A.V. Ishchenko, A.V. Selivanova, V.V. Kaichev, S.V. Cherepanova, T.A. Krieger, M.V. Arapova, A.-C. Roger, A. Adamski, V.A. Sadykov, Methane dry reforming over Ni catalysts supported on Ce–Zr oxides prepared by a route involving supercritical fluids, Open Chemistry 15 (2017) 412-425
  16. P. Legutko, T. Jakubek, W. Kaspera, P. Stelmachowski, Z. Sojka, A. Kotarba, Strong Enhancement of deSoot Activity of Transition Metal Oxides by Alkali Doping – Additive Effects of Potassium and Nitric Oxide, Topics in Catalysis 60 (2017) 162-170
    17. 2016
  17. G. Grzybek, S. Wójcik, P. Legutko, J. Gryboś, P. Indyka, B. Leszczyński, A. Kotarba, Z. Sojka, Thermal stability and repartition of potassium promoter between the support and active phase in the K-Co2.6Zn0.4O4|α-Al2O3 catalyst for N2O decomposition: crucial role of activation temperature on catalytic performance, Applied Catalysis B: Environmental 205 (2017) 597-604
    18. 2016
  18. V.A. Sadykov, M.N. Simonov, N.V. Mezentseva, S.N. Pavlova, Y.E. Fedorova, A.S. Bobin, Y.N. Bespalko, A.V. Ishchenko, T.A. Krieger, T.S. Glazneva, T.V. Larina, S.V. Cherepanova, V.V. Kaichev, A.A. Saraev, Y.A. Chesalov, A.N. Shmakov, A.-C. Roger, A. Adamski, Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming, Open Chemistry 14 (2016) 363-376
  19. K. Hąc-Wydro, K. Szydło
    The influence of environmentally friendly pesticide – Eucalyptol – alone and in combination with terpinen-4-ol – on model bacterial membranes
    Colloids and Surfaces B: Biointerfaces 146 (2016) 918–923 DOI:10.1016/j.colsurfb.2016.07.044
  20. P. Stelmachowski, P. Legutko, A. Kopacz, T. Jakubek, P. Indyka, P. Pietrzyk, M. Wojtasik, J. Markowski, W. Krasodomski, L. Ziemiański, G. Żak, Z. Sojka, A. Kotarba
    Role of chain length of the capping agents of iron oxide based fuel borne catalysts in the enhancement of soot combustion activity
    Applied Catalysis B: Environmental 199 (2016) 485–493 DOI:10.1016/j.apcatb.2016.06.056
  21. T. Jakubek, W. Kaspera, P. Legutko, P. Stelmachowski, A. Kotarba
    How to Efficiently Promote Transition Metal Oxides by Alkali Towards Catalytic Soot Oxidation
    Topics in Catalysis 59 (2016) 1083-1089 DOI: 10.1007/s11244-016-0595-x
  22. K. Hąc-Wydro, I. Pałasińska, P. Miśkowiec
    The comparative studies on the ability of anionic surfactants to bind lead(II) ions
    Journal of Molecular Liquids 219 (2016) 1071–1077 DOI: 10.1016/j.molliq.2016.02.067
  23. M. Flasiński, B. Konderla, M. Broniatowski, P. Wydro
    Sterol-phospholipid hybrids at the air/water interface - studies on properties and interactions with parent lipid molecules
    Langmuir 32 (2016) 4095 - 4102 DOI: 10.1021/acs.langmuir.5b04311
  24. K. Hąc-Wydro, A. Sroka, K. Jabłońska
    The impact of auxins used in assisted phytoextraction of metals from the contaminated environment on the alterations caused by lead(II) ions in the organization of model lipid membranes
    Colloids and Surfaces B: Biointerfaces 143 (2016) 124–130 DOI: 10.1016/j.colsurfb.2016.03.018
  25. M. Flasiński, M. Gawryś, M. Broniatowski, P. Wydro
    Studies on the interactions between parabens and lipid membrane components in monolayers at the air/aqueous solution interface
    Biochimica et Biophysica Acta (BBA) - Biomembranes 1858 (2016) 836–844 DOI: 10.1016/j.bbamem.2016.01.002
  26. M. Broniatowski, K. Sobolewska, M. Flasiński, P. Wydro
    Studies on the interactions of bisphenols with anionic phospholipids of decomposer membranes in model systems
    Biochimica et Biophysica Acta (BBA) - Biomembranes 1858 (2016) 756–766 DOI: 10.1016/j.bbamem.2016.01.017
    27. 2015
  27. M. Flasiński, M. Bartosik, S. Kowal, M. Broniatowski, P. Wydro
    Characteristics of the influence of auxins on physicochemicalproperties of membrane phospholipids in monolayers at theair/aqueous solution interface
    Colloids and Surfaces B: Biointerfaces 136 (2015) 1131-1138 DOI: 10.1016/j.colsurfb.2015.11.022
  28. M.M. Fiuk, A. Adamski
    Activity of MnOx–CeO2 Catalysts in Combustion of Low Concentrated Methane
    Catal. Today 257 (2015) 131-135 DOI: 10.1016/j.cattod.2015.01.029
  29. B. Szala, T. Bajda, J. Matusik, K. Zięba, B. Kijak
    BTX sorption on Na-P1 organo-zeolite as a process controlled by the amount of adsorbed HDTMA
    Microporous and Mesoporous Materials 202 (2015) 115-123 DOI: 10.1016/j.micromeso.2014.09.033
  30. P. Miśkowiec, A. Łaptaś, K. Zięba
    Soil pollution with heavy metals in industrial and agricultural areas: a case study of Olkusz District
    Journal of Elementology 20 (2015) 353-362 DOI: 10.5601/jelem.2014.19.3.691
  31. P. Stelmachowski, A. Kopacz, P. Legutko, P. Indyka, M. Wojtasik, L. Ziemiański, G. Żak, Z. Sojka, A. Kotarba
    The role of crystallite size of iron oxide catalyst for soot combustion
    Catalysis Today 257 (2015) 111-116 DOI: 10.1016/j.cattod.2015.02.018
  32. F. Zasada, W. Piskorz, P. Stelmachowski, P. Legutko, A. Kotarba, Z. Sojka
    Density Functional Theory Modeling and Time-of-Flight Secondary Ion Mass Spectrometric and X-ray Photoelectron Spectroscopic Investigations into Mechanistic Key Events of Coronene Oxidation: Toward Molecular Understanding of Soot Combustion
    Journal of Physical Chemistry C 119 (2015) 6568–6580 DOI: 10.1021/jp512018z
  33. T. Jakubek, W. Kaspera, P. Legutko, P. Stelmachowski, A. Kotarba
    Surface versus bulk alkali promotion of cobalt-oxide catalyst in soot oxidation
    Catalysis Communications 71 (2015) 37–41 DOI: 10.1016/j.catcom.2015.08.014
  34. P. Stelmachowski, P. Legutko, T. Jakubek, P. Indyka, Z. Sojka, L. Holmlid, A. Kotarba
    Emission of highly excited electronic states of potassium from cryptomelane nanorods
    Physical Chemistry Chemical Physics 17 (2015) 26289-26294 DOI: 10.1039/C5CP04108B
  35. K. Hąc-Wydro, P. Wydro, A. Cetnar, G. Włodarczyk
    Phospatidylserine or ganglioside - Which of anionic lipids determines the effect of cationic dextran on lipid membrane?
    Colloids and Surfaces B: Biointerfaces 126 (2015) 204-209 DOI: 10.1016/j.colsurfb.2014.12.031
  36. M. Broniatowski, P. Mastalerz, M. Flasiński
    Studies of the interactions of ursane-type bioactive terpenes with the model of Escherichia coli inner membrane - Langmuir monolayer approach
    Biochimica et Biophysica Acta - Biomembranes 1848 (2015) 469-476 DOI: 10.1016/j.bbamem.2014.10.024
  37. M. Broniatowski, M. Flasiński, P. Wydro, P. Fontaine
    Grazing incidence diffraction studies on the interactions between ursane-type antimicrobial triterpenes and bacterial anionic phospholipids
    Colloids and Surfaces B: Biointerfaces 128 (2015) 561-567 DOI: 10.1016/j.colsurfb.2015.03.009
  38. K. Hąc-Wydro, M. Flasiński
    The studies on the toxicity mechanism of environmentally hazardous natural (IAA) and synthetic (NAA) auxin - the experiments on model Arabidopsis thaliana and rat liver plasma membranes
    Colloids and Surfaces B: Biointerfaces 130 (2015) 53-60 DOI: 10.1016/j.colsurfb.2015.03.064
  39. K. Hąc-Wydro, K. Wąder, M. Mach, M. Flasiński, P. Wydro
    The influence of cholesterol precursor - desmosterol - on artificial lipid membranes
    Biochimica et Biophysica Acta - Biomembranes 1848 (2015) 1639-1645 DOI: 10.1016/j.bbamem.2015.04.017
  40. M. Broniatowski, M. Flasiński, K. Hąc-Wydro
    Antagonistic effects of α-tocopherol and ursolic acid on model bacterial membranes
    Biochimica et Biophysica Acta - Biomembranes 1848 (2015) 2154-2162 DOI: 10.1016/j.bbamem.2015.05.009
  41. M. Flasiński, P. Wydro, M. Broniatowski, K. Hąc-Wydro, P. Fontaine
    Crucial role of the double bond isomerism in the steroid B-ring on the membrane properties of sterols. Grazing Incidence X-ray Diffraction and Brewster angle microscopy studies
    Langmuir 31 (2015) 7364-7373 DOI: 10.1021/acs.langmuir.5b00896
    42. 2014
  42. M. Rutkowska, L. Chmielarz, D. Macina, Z. Piwowarska, B. Dudek, A. Adamski, S. Witkowski, Z. Sojka, L. Obalová, C.J. Van Oers, P. Cool
    Catalytic Decomposition and Reduction of N2O over Micro-mesoporous Materials Containing Beta Zeolite Nanoparticles
    Appl. Catal. B 146 (2014) 112-122 DOI: 10.1016/j.apcatb.2013.05.005
  43. P. Miśkowiec, A. Łaptaś, W. Tłuściak
    Metale ciężkie w wodach i osadach rzecznych Prądnika i Sąspówki
    Prądnik. Prace i Materiały Muzeum im. Prof. Wł. Szafera 24 (2014) 139-150
  44. P. Miśkowiec, A. Łaptaś, M. Ślusarska
    Metale ciężkie w glebach doliny Prądnika
    Prądnik. Prace i Materiały Muzeum im. Prof. Wł. Szafera 24 (2014) 131-138
  45. Z. Olech, W. Zaborska, M. Kot
    Jack bean urease inhibition by crude juices of Allium and Brassica plants. Determination of thiosulfinates
    Food Chem. 145 (2014) 154-160 DOI : 10.1016/j.foodchem.2013.08.044
  46. M. Broniatowski, M. Flasiński, K. Zięba, P. Miśkowiec
    Interactions of pentacyclic triterpene acids with cardiolipins and related phosphatidylglycerols in model systems
    Biochim. Biophys. Acta Biomembranes 1838 (2014) 2530-2538 DOI: 10.1016/j.bbamem.2014.05.027
  47. M. Broniatowski, M. Flasiński, K. Zięba, P. Miśkowiec
    Langmuir monolayer studies of the interaction of monoamphiphilic pentacyclic triterpenes with anionic mitochondrial and bacterial membrane phospholipids — Searching for the most active terpene
    Biochim. Biophys. Acta Biomembranes 1838 (2014) 2460-2472 DOI: 10.1016/j.bbamem.2014.05.009
  48. M. Flasiński, P. Wydro, M. Broniatowski
    Lyso-phosphatidylcholines in Langmuir monolayers – Influence of chain length on physicochemical characteristics of single-chained lipids
    Journal of Colloid and Interface Science 418 (2014) 20–30 DOI: 10.1016/j.jcis.2013.12.003
  49. K. Hąc-Wydro, P. Wydro, M. Flasiński
    The comparison of zymosterol vs cholesterol membrane properties–The effect of zymosterol on lipid monolayers
    Colloids Surf. B Biointerfaces, 123 (2014) 524–532 DOI: 10.1016/j.colsurfb.2014.09.054
  50. M. Flasiński, K. Hąc-Wydro, M. Broniatowski
    Incorporation of pentacyclic triterpenes into mitochondrial membrane-Studies on the interactions in model 2D lipid systems
    J. Phys. Chem. B 118 (2014) 12927−12937 DOI: 10.1021/jp508743j
  51. K. Hąc-Wydro, K. Luty
    Miscibility and interactions of animal and plant sterols with choline plasmalogen in binary and multicomponent model systems
    Colloids Surf. B Biointerfaces 116 (2014) 138–146 DOI: 10.1016/j.colsurfb.2013.12.059
  52. M. Flasiński, K. Hąc-Wydro
    Natural vs synthetic auxin: Studies on the interactions between plant hormones and biological membrane lipids
    Environ. Res. 133 (2014) 123–134 DOI: 10.1016/j.envres.2014.05.019
  53. M. Flasiński, K. Hąc-Wydro, P. Wydro, P. Dynarowicz-Łątka
    Influence of platelet-activating factor, lyso-platelet-activating factor and edelfosine on Langmuir monolayers imitating plasma membranes of cell lines differing in susceptibility to anti-cancer treatment: the effect of plasmalogen level
    J. R. Soc. Interface 11 (2014) 20131103 DOI: 10.1098/rsif.2013.1103
  54. P. Dynarowicz-Łątka, K. Hąc-Wydro
    Edelfosine in Membrane Environment - the Langmuir Monolayer Studies
    Anti-Cancer Agents in Medicinal Chemistry 14 (2014) 499-508 DOI: 10.2174/1871520614666140309230722
  55. A. Ryguła, P. Miśkowiec
    Chemometric Analysis of Raman and IR Spectra of Natural Dyes
    "Optical Spectroscopy and Computational Methods in Biology and Medicine", ed. M. Barańska, Springer, 2014, ISBN: 978-9400778313, pp. 279-308
    56. 2013
  56. P. Miśkowiec, A. Łaptaś, A. Seroka
    Wybrane parametry fizykochemiczne wód ze źródeł doliny Prądnika
    Prądnik. Prace i Materiały Muzeum im. Prof. Wł. Szafera 23 (2013) 111-119 link