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Group of Analytical Flow Techniques

 
 

group members
 
Paweł Nowak, Dr habil, PhD
 
Renata Wietecha-Posłuszny, Dr habil, PhD
 
Michał Woźniakiewicz, Dr habil, PhD
 
Małgorzata Król, PhD
 
Aneta Woźniakiewicz, PhD
 
Anna Bonczyk, Msc
 
Alicja Chromiec, Msc
 
Małgorzata Gołąb, Msc
 
Joanna Pluta, Msc
 
Marcelina Rusin, Msc
 
Anna Sałdan, Msc
 
Gabriela Tajduś, MSc, Eng

basic information
 

 



[Main research subjects]   [Present research topics]
[Selected publications]   [Selected conference presentations]
[Research projects]

Main research subjects

  • Novel calibration methods in flow analysis
  • Application of flow techniques to the sample preconcentration,
  • Flow micro-systems and their application in forensic chemistry
  • Identification examinations of criminalistic traces
  • Novel analytical procedures of biological tissues

Present research topics

  • Development of novel calibration strategy in analytical chemistry
  • Recovery method as a way for evaluation of analytical accuracy – conceptual an experimental investigations
  • Examinations on new titration procedures in flow analysis
  • Preparation of new sorbents and their application to improvement of analytical conditions for determination of copper and cadmium with the use of flow techniques
  • Construction of a flow micro-system for determination of psychotropic drugs in saliva
  • Development of novel techniques for extraction of psychotropic drugs from biological tissues
  • Identification and comparison analysis of inkjet printer inks by capillary electrophoresis
  • Development of novel methods for analysis of biological tissues by ICP-MS and ICP-OES techniques

Selected publications

  1. K. Góra-Marek, H. Mrowiec, S. Walas, “Cobalt Sites in Zeolites FAU – IR Investigations”, J. Mol. Struct., 923, 67-71 (2009).
  2. M. Filek, M. Zembala, H. Hartikainen Z. Mieszalski, A. Kornaś, R. Wietecha-Posłuszny, S. Walas, „Changes in Wheat Plastid Membrane Properties Induced by Cadmium and Selenium in Presence/Absence of 2,4-dichlorophenoxyacetic Acid”, Plant Cell Tiss. Organ. Cult., 96, 19-28 (2009).
  3. M. Zadrożna, M. Gawlik, B. Nowak, A. Marcinek, H. Mrowiec , S. Walas,R. Wietecha-Posłuszny, P. Zagrodzki, „Antioxidants Activities and Concentration of Selenium, Zinc and Copper in Preterm and IUGR Human Placentas”, J. Trace Elem. Med. Biol., 23, 144-148 (2009).
  4. M. Szafarska, M. Woźniakiewicz, M. Pilch, J. Zięba-Palus, P. Kościelniak, “Computer Analysis of ATR-FTIR Spectra of Paint Samples for Forensic Purposes”, J. Molec. Struct., 924–926, 504–513 (2009).
  5. B. Trzcińska, J. Zięba-Palus, P. Kościelniak, "Application of Microspectrometry in Visible Range to Differentiation of Car Solid Paints for Forensic Purposes", J. Molec. Struct., 924–926, 393–399 (2009).
  6. R. Wietecha-Posłuszny, J. Dobrowolska, P. Kościelniak, P. Zagrodzki, „Determination of Selenium as a Biomarker of Thyroid Cancer by HG-AFS Metod”, Acta Chim. Slov., 56, 441-446 (2009).
  7. J. M. Milczarek, M. Dziadosz, J. Zięba-Palus, “Way to Distinguish Car Paint Traces Based on Epoxy Primer Layers Analysis by Pyrolysis - Gas Chromatography - Mass Spectrometry (Py-GC/MS)”, Chem. Anal., 54, 173-185 (2009.
  8. M. Wójtowicz, J. Kozak, K. Danielewska, P. Kościelniak, „Flow Injection Titration Basing on the Merging-zone Technique”, Talanta, 79, 1006–1010 (2009).
  9. A. Tobiasz, S. Walas, B. Trzewik, P. Grzybek, M. M. Zaitz, M. Gawin, H. Mrowiec, „Cu(II)-Imprinted Styrene-Divinylbenzene Beads as a New Sorbent For Flow Injection-Flame Atomic Absorption Determination of Copper”, Microchemical Journal, 93, 87-92 (2009).
  10. K. Madej, A. Biedroń, A. Garbacik, „Study of Separation and Extraction Conditions for Five Neuroleptic Drugs by an LLE-HPLC-DAD Method in Human Plasma”, Journal of Liquid Chromatography & Related Technologies, 32, 3025-3037 (2009).
  11. M. Woźniakiewicz, J. Kuczara, P. Kościelniak, „Determination of Fluoxetine in Blood Samples by High-performance Liquid Chromatography Using a Derivatization Reagent”, Chem. Anal. (Warsaw), 54, 667-677 (2009).
  12. M. Herman, P. Kościelniak, M. Wieczorek, M. Stafiński, M. Matuszek, “A Spectrophotometric Method for Determination of Chlorites in Drinking Water with the Use of Flow Technique”, Chem Anal (Warsaw), 54, 907-919 (2009).
  13. J. Dobrowolska, M. Dehnhardt, A. Matusch, M. Zoriy, N. Palomero-Gallagher, P. Kościelniak, K Zilles, J. S. Becker, “Quantitative Imaging of Zinc, Copper and Lead in Three Distinct Regions of the Human Brain by Laser Ablation Inductively Coupled Plasma Mass Spectrometry”, Talanta, 74, 717-723 (2008).
  14. J. S. Becker, H. Sela, J. Dobrowolska, M. Zoriy, J. Su. Becker, “Recent Applications on Isotope Ratio Measurements by ICP-MS and LA-ICP-MS on Biological Samples and Single Particles”, Int. J. Mass Spectrom., 270, 1–7 (2008).
  15. J. Zięba-Palus, G. Zadora, J. M. Milczarek, P. Kościelniak, „Pyrolysis-gas Chromatography/Mass Sectrometry Analysis as a Useful tool in Forensic Examination of Automotive Paint Traces”, J. Chromatogr. A, 1179, 41-46 (2008).
  16. J. Zięba-Palus, G. Zadora, J. M. Milczarek, “Differentiation and Evaluation of Evidence Value of Styrene Acrylic Urethane Topcoat Car Paints Analysed by Pyrolytic Gas Chromatography”, J. Chromatogr. A, 1179, 47-58 (2008).
  17. K. Madej, P. Kościelniak, „Review of Analytical Methods for Identification and Determination of Phenothiazines and Tricyclic Antidepressants”, Crit. Rev. Anal. Chem., 38, 51-67 (2008)
  18. J. Zięba-Palus, J. M. Milczarek, P. Kościelniak, “Application of Infrared Spectroscopy and Pyrolytic Gas Chromatography in Examination of Automobile Paint Samples”, Chem. Anal. (Warsaw), 52, 109-121 (2008).
  19. M. Woźniakiewicz, R. Wietecha-Posłuszny, A. Garbacik, P. Kościelniak, „Microwave-Assisted Extraction of Tricyclic Antidepressants from Human Serum Followed by High Performance Liquid Chromatography Determination”, J. Chromatogr. A, 1190, 52–56 (2008).
  20. S. Walas, A. Tobiasz, M. Gawin, B. Trzewik, M. Strojny, H. Mrowiec, „Application of a Metal Ion-imprinted Polymer Based on Salen-Cu Complex to Flow Injection Preconcentration and FAAS Determination of Copper”, Talanta, 76, 96-1001 (2008).
  21. J. Kozak, M. Wójtowicz, A. Wróbel, P. Kościelniak, „Novel Approach to Calibration by the Complementary Dilution Method with the Use of a Monosegmented Sequential Injection System”, Talanta, 77, 587-592 (2008).
  22. M. Wójtowicz, J. Kozak, D. Górnacka, P. Kościelniak, “Application of Flow Injection Gradient Titration Based on a Sample and Standard Dilution to The Determination of Total Acidity in Vinegars and Soft Drinks”, Anal. Sci., 24, 1593-1597 (2008).
  23. J. S. Becker, J. Dobrowolska, M. Zoriy, A. Matusch, „Imaging of Uranium on Rat Brain Sections Using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-IMS): A New Tool for the Study of Critical Substructures Affined to Heavy Metals in Tissues”, Rapid Commun. Mass Sp., 22, 2768-2772 (2008).
  24. M. Filek, M. Zembala, Z. Mieszalski, A. Kornaś, R. Wietecha-Posłuszny, S. Walas, „Changes in Wheat Plastid Membrane Properties Induced by Cadmium and Selenium in Presence/Absence of 2,4-dichlorophenoxyacetic Acid”, Plant Cell Tiss. Organ. Cult., 96, 19-28 (2009);
  25. I. López-García, J. Kozak, M. Hernández-Córdoba, “Use of Membrane Micropumps for Introducing the Sample Solution in Flame Atomic Absorption Spectrometry”, Talanta, 71, 1369-1374 (2007)
  26. I. López-García, J. Kozak, M. Hernández-Córdoba, “Nonconventional Semiautomated Standard Addition Procedure Based on Membrane Micropumps for Flame Atomic Absorption Spectrometry”, Spectrosc. Lett., 40, 15-26 (2007)
  27. J. S. Becker, J. Su., Becker, M. Zoriy, J. Dobrowolska, M. Dehnhardt, A. Matusch, “New Developments in Laser Ablation Inductively Coupled Plasma Mass Spectrometry For Brain Research and Life Sciences”, Eur. J. Mass. Spectrom., 13, 1-6 (2007)
  28. J. S. Becker, M. Zoriy, J. Su. Becker, J. Dobrowolska, M. Dehnhardt, A. Matusch “Elemental Imaging Mass Spectrometry of Thin Sections of Tissues and Analysis of Brain Proteins in Gels by Laser Ablation Inductively Coupled Plasma Mass Spectrometry”, Phys. Status Solidi C, 4, 1775-1784 (2007)
  29. J. S. Becker, A. Matusch, J. Dobrowolska, M. V. Zoriy, “New Staining Technique in Medicine Using Heavy Metals: Imaging of Uranium and Neodymium in Rat Brain Sections By LA-ICP-MS, J. Anal. At. Spectrom., 22, 1-9, (2007)
  30. P. Kościelniak, M. Wieczorek, J. Kozak, M. Herman, “Versatile Flow Injection Manifold for Analytical Calibration”, Anal. Chim. Acta, 600, 6-13 (2007)
  31. M. Wójtowicz, J. Kozak, P. Kościelniak, “Novel Approaches to Calibration by Flow Injection Gradient Titration”, Anal. Chim. Acta, 600, 78-83 (2007)
  32. P. Zagrodzki, R. Ratajczak, R. Wietecha-Posłuszny, “The Interaction Between Selenium Status, Sex Hormones, and Thyroid Metabolism in Adolescent Girls During Luteal Phase of Menstrual Cycle”, Biol. Trace Elem. Res., 60, 51-60 (2007)
  33. M. Woźniakiewicz, J. Kuczara, P. Kościelniak, “Determination of Desipramine and Nortriptyline in Blood by Means of the HPLC-DAD Method Using 7,7,8,8-Tetracyanoquinodimethane (TCNQ) as a Derivatisation Agent”, Problems of Forensic Sciences, 69, 90-97 (2007)

Selected conference presentations

  1. 5th European Academy of Forensic Science Conference, Glasgow, UK, 8-11 September 2009; M. Szafarska, A. Solarz, R. Wietecha-Posłuszny, M. Woźniakiewicz, P. Kościelniak, poster „Optimization of extraction of inkjet inks from paper for forensic purposes”
  2. 5th European Academy of Forensic Science Conference, Glasgow, UK, 8-11 September 2009; M. Woźniakiewicz, R.Wietecha-Posłuszny, A. Garbacik, P. Kościelniak, poster #8222;Microwave-assisted alkaline hair hydrolysis and liquid extraction of basic drugs from human hair”
  3. „Flow Analysis XI”, Pollensa, Spain, 14-18 September 2009 r.; J. Kozak, J. Gutowski, M. Wieczorek, P. Kościelniak, „New method of simultaneous determination of Fe(II) and Fe(III) in water using flow injection system”
  4. „Flow Analysis XI”, Pollena, Spain, 14-18 September 2009; J. Kozak, M. Wieczorek, J. Kozioł, P. Kościelniak, “Integrated calibration method – comparison of various flow approaches”
  5. 9th International Symposium on Forensic Sciences, Piestany, Slovakia, 29 September - 2 October 2009; M. Szafarska, R. Wietecha-Posłuszny, M. Woźniakiewicz, P. Kościelniak, oral „Application of capillary electrophoresis to the discrimination of inkjet printing inks”
  6. 9th International Symposium on Forensic Sciences, Piestany, Slovakia, 29 September - 2 October 2009 r.; R. Wietecha-Posłuszny, A. Garbacik, M. Woźniakiewicz, P. Kościelniak, oral „Innovative extraction method for isolation of psychotropic drugs from human hair”
  7. Conference “Sequential Injection Analysis ’08”, Hradec Kralove, Czech Republic, 2-4 June 2008 r.; J. Kozak, P. Kościelniak, poster „Novel Approach to Calibration in Sequential Injection Analysis”
  8. 9th European Conference on Research in Chemical Education (ECRICE), Istanbul, Turkey, 6-9 July 2008; A. Bader, M. Rothweil, I. Maciejowska, R. Wietecha-Posłuszny, oral: ,,How to Redouble Pupil’s Motivation? - Crime Scene Investigation Exercise”
  9. 9th European Conference on Research in Chemical Education (ECRICE), Istanbul, Turkey, 6-9 July 2008; M. Szafarska, R. Wietecha-Posłuszny, M. Woźniakiewicz, P. Kościelniak, poster: ,,Justice Above All Else – Analytical Chemistry in a Forensic Costume”
  10. 9th European Conference on Research in Chemical Education (ECRICE), Istanbul, Turkey, 6-9 July 2008; R. Wietecha-Posluszny, P. Kościelniak, poster: ,,A Forensic Laboratory Class - Application of the AFS Method to Post-mortem Examination of Acute Toxic Metal Poisoning”
  11. EUCMOS 2008, Opatja, Croatia, 1-5 września 2008 r.; M. Szafarska, M. Woźniakiewicz, M. Pilch, J. Zięba-Palus, P. Kościelniak, poster: „Computer Analysis of ATR-FTIR Spectra of Paint Samples for Forensic Purposes”
  12. 27th International Symposium on Chromatography, Münster, Germany, 22-25 September 2008.; J. M. Milczarek, J. Zięba-Palus, poster pt. “Examination of Spray Paints on Plasters by the Use of Pyrolysis-Gas Chromatography-Mass Spectrometry (Py-GC/MS)”
  13. 27th International Symposium on Chromatography, Münster, Germany, 22-25 September 2008 r.; J. M. Milczarek, J. Zięba-Palus, poster: “Application of derivatisation process in examination of acrylic melamine and alkyd melamine car paints by pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS)”
  14. ESAS ’08 European Symposium on Atomic Spectrometry ESAS ’08, Weimar, Germany, 28 September - 1 October 2008; A. Tobiasz, S.Walas, M. Gawin, H. Mrowiec, , M.M. Zaitz, B. Trzewik, poster: „Copper Imprinted Styrene-Divinylobenzene Beads as a New Sorbent for Flow Injection-Flame Atomic Absorption Determination”
  15. ESAS ’08 European Symposium on Atomic Spectrometry ESAS ’08, Weimar, Germany, 28 September - 1 October 2008 r.; M. Gawin, M. Bryłka, H. Mrowiec, A. Tobiasz, B. Trzewik, S. Walas, poster: „Flow Injection Microcolumn Preconcentration of Cadmium(II) from Aqueous Samples with the Use of Salen Impregnated Silica Gel”
  16. 15th International Conference on Flow Injection Analysis, Nagoja, Japan, 28 September - 3 October 2008; J. Kozak, M. Wieczorek, P. Kościelniak, oral: „Calibration by the Integrated Method with the Use of a Monosegmented Sequential Injection System”
  17. 15th International Conference on Flow Injection Analysis, Nagoja, Japan, 28 September - 3 October 2008; M. Wójtowicz, J. Kozak, K. Danielewska, P. Kościelniak, poster: „Novel Approach to Titration in Flow Injection Analysis Basing on the Merging Zones Technique”
  18. International Symposium on Environmental Analytical Chemistry ISEAC 35, Gdańsk, Poland, 22-26 June 2008; M. Herman, E. Mruk, M. Wieczorek, P. Koscielniak, poster: "Flow Method for Indirect Spectrophotometric Determination of Chlorites in Water"
  19. European Winter Plasma Conference, Taormina, Italy, 18-23 February 2007; J. Dobrowolska, M. Dehnhardt, A. Matusch, M. Zoriy, P. Kościelniak, K. Zilles, J.S. Becker, poster: „Development and Application of Micro-analytical Method for Investigation of Brain Tissue by LA-ICP-MS”
  20. European Winter Plasma Conference, Taormina, Italy, 18-23 February 2007; J. Dobrowolska, A. Matusch , M. V. Zoriy, J. S. Becker, poster: „New Staining Technique in Medicine Using Heavy Metals: Imaging of Uranium”
  21. European Winter Plasma Conference, , Italy, 18-23 February 2007; M.V. Zoriy, A. Matusch , C. Depboylu, J. Dobrowolska, J. S. Becker, poster: „Imaging of Selenium, Copper and Zinc in Thin Sections of Biological Tissues (Slugs-genus Arion) Measured by LA-ICP-MS”
  22. European Winter Plasma Conference, , Italy, 18-23 February 2007; J.S. Becker, M. Zoriy, J. Dobrowolska, J. Su. Becker, H. Sela, oral: “Progress on Analysis of Stable Isotopes & Radionuclides by ICP-MS and LA-ICP-MS”
  23. 13th International Symposium on Separation Sciences, Štrbské Pleso, Slovakia, 27-29 June 2007; J. Zięba-Palus, G. Zadora *, J.M. Milczarek, oral: “Differenation of Topcoat Car Paints on the Basis of Results Obtained by Py-Gc/Ms”
  24. 13th International Symposium on Separation Sciences, Štrbské Pleso , Slovakia, 27-29 June 2007; J. Zięba-Palus, G. Zadora, J.M. Milczarek, P. Kościelniak, oral: “Py-GC/MS Analysis the Useful Tool in Forensic Examination of Paint Traces”
  25. 2nd European Variety in Chemistry Education”, Prague, Czech Republic, 27-30 June 2007; I. Maciejowska, M. Woźniakiewicz, R. Wietecha-Posłuszny, A. Strzelecki, M. Słoboda, P. Kościelniak, poster: „The Flash MX Supported Manual for Forensic Chemistry Students”
  26. XIV International Conference on Flow Injection Analysis Including Related Techniques, Berlin, Germany, 3-7 September 2007; J. Kozak, A, Wróbel, M. Wójtowicz, poster: „Complementary Dilution Calibration Method in a Monosegmented Sequential Injection System”.
  27. Euroanalysis XIV, Antwerp, Belgium, 9-14 September, 2007; M. Wójtowicz, J. Kozak, poster: „Single-Point Multi-Line Flow Injection Titration Procedure”.
  28. Euroanalysis XIV, Antwerp, Belgium, 9-14 September, 2007; M. Gawin, H. Mrowiec, B. Trzewik, A. Telk, S. Walas, poster: „Salen Modified Silica Gel as a new Sorbent for Flow Injection Preconcentration of Cadmium".
  29. 8th International Symposium on Forensic Sciences, Šamorín-Čilistov, Slovakia, 26-29 September 2007; M. Szafarska, M. Woźniakiewicz, P. Kościelniak, J. Zięba-Palus, M. Pilch, oral: „The method of Subtraction and Normalization of ATR-FTIR Spectra in Forensic Examination of Paints”.
  30. 8th International Symposium on Forensic Sciences, Šamorín-Čilistov, Slovakia, 26-29 September 2007; J. Dobrowolska, R. Wietecha-Posłuszny, P. Kościelniak, poster pt. ,,HG-AFS Determination of Arsenic in Blood and Urine of Drug Addicted Persons”.

Research projects

  • POIG.01.03.01-14-014/08 pt. „Micro i nano-systems in chemistry and biomedical diagnostics (MNS-DIAG)” granted by Operational Program Innovative Economy 2007-2013, Subproject 1A „Lab-on-a-chip with electrochemical detection for the analysis of saliva samples for psychoactive substances determination”, 720 000 PLN
  • TEMPUS project (JEP_41105_2006) „Education System in Forensic Sciences for the Republic of Macedonia” (EDUFORMAK);
  • 3 T08D 010 28 „Nowe, stabilne strukturalnie, kompozytowe materiały katodowe dla akumulatorów litowych otrzymane na bazie spinelu manganowego podstawionego siarką”
  • 0 T00C 013 26 „Identyfikacja i rozróżnianie śladów lakierowych metodą pirolitycznej chromatografii gazowej (Py-GC/MS) dla potrzeb wymiaru sprawiedliwości” ;
  • 3 T09A 102 27 „Badania w zakresie kalibracji analitycznej przy użyciu uniwersalnego urządzenia wstrzykowo-przepływowego” ;
  • 0 N204 0003 33 „Zastosowanie elektroforezy kapilarnej jako narzędzia w badaniach kryminalistycznych dokumentów drukowanych atramentami” (grant zwykły);
  • N204 2717 33 „Otrzymywanie i charakterystyka polimerów dopasownych jonowo pod kątem zatężania metali ciężkich (Cu, Cd) techniką wstrzykowo-przepływową” ,

 

Modified by: Mariusz Pilch, 2020-04-14 08:43:37
   

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